select a.id, a.chemical_cn, a.other_chemical_cn, a.chemical_en, a.other_chemical_en, a.cas, a.type, a.detonator_profession1, a.detonator_profession1_concentration, a.detonator_profession1_CAS_No, a.detonator_profession2, a.detonator_profession2_concentration, a.detonator_profession2_CAS_No, a.detonator_profession3, a.detonator_profession3_concentration, a.detonator_profession3_CAS_No, a.detonator_profession4, a.detonator_profession4_concentration, a.detonator_profession4_CAS_No, a.detonator_profession5, a.detonator_profession5_concentration, a.detonator_profession5_CAS_No, a.hazard_category, a.Invasion_route, a.health_hazards, a.environmental_hazards, a.explosion_hazard, a.skin_contact, a.eye_contact, a.inhalation, a.ingestion, a.hazard_characteristics, a.hazardous_combustion_products, a.fire_extinguishing_method, a.fire_fighting, a.emergency_actions, a.operational_considerations, a.storage_precautions, a.MAC, a.PC_TWA, a.PC_STEL, a.TLV_C, a.TLV_TWA, a.TLV_STEL, a.monitoring_methods, a.engineering_control, a.respiratory_protection, a.eye_protection, a.physical_protection, a.hand_protection, a.other_protection, a.appearance_and_shape, a.ph_value, a.melting_point, a.boiling_point, a.relative_density, a.relative_vapor_density, a.saturated_vapor_pressure, a.heat_of_combustion, a.critical, a.critical_pressure, a.octanol_water_partition_coefficient, a.flash_point, a.Ignition_temperature, a.lower_explosion_limit, a.upper_explosion_limit, a.solubility, a.main_uses, a.stability, a.forbidden_mixtures, a.avoid_contact_conditions, a.aggregation_hazards, a.decomposition_products, a.nature_of_waste, a.disposal_methods, a.deprecation_considerations, a.dangerous_goods_number, a.un_number, a.packaging_category, a.packaging_logo, a.packaging_method, a.shipping_precautions, a.regulatory_information, a.critical_value, b.id as id, b.msds as msds, b.acute_toxicity as acute_toxicity, b.rats_oral_LD as rats_oral_LD, b.rats_percutaneous_LD as rats_percutaneous_LD, b.rats_subcutaneous_LD as rats_subcutaneous_LD, b.rats_venous_LD as rats_venous_LD, b.rats_intraperitoneal_LD as rats_intraperitoneal_LD, b.mice_oral_LD as mice_oral_LD, b.mice_percutaneous_LD as mice_percutaneous_LD, b.mice_venous_LD as mice_venous_LD, b.mice_intraperitoneal_LD as mice_intraperitoneal_LD, b.guinea_pigs_oral_LD as guinea_pigs_oral_LD, b.guinea_pigs_percutaneous_LD as guinea_pigs_percutaneous_LD, b.guinea_pigs_subcutaneous_LD as guinea_pigs_subcutaneous_LD, b.guinea_pigs_venous_LD as guinea_pigs_venous_LD, b.guinea_pigs_intraperitoneal_LD as guinea_pigs_intraperitoneal_LD, b.rabbit_oral_LD as rabbit_oral_LD, b.rabbit_percutaneous_LD as rabbit_percutaneous_LD, b.rabbit_subcutaneous_LD as rabbit_subcutaneous_LD, b.rabbit_venous_LD as rabbit_venous_LD, b.rabbit_intraperitoneal_LD as rabbit_intraperitoneal_LD, b.other_animal_LD as other_animal_LD, b.LD as LD, b.LDL0 as LDL0, b.TDL0 as TDL0, b.rats_inhale_LC as rats_inhale_LC, b.rats_inhale_LCL0 as rats_inhale_LCL0, b.mice_inhale_LC as mice_inhale_LC, b.mice_inhale_LCL0 as mice_inhale_LCL0, b.mice_inhale_TDL0 as mice_inhale_TDL0, b.people_inhale_LCL0 as people_inhale_LCL0, b.people_inhale_TDL0 as people_inhale_TDL0, b.IDLH as IDLH, b.other_animal_LC_50 as other_animal_LC_50, b.other_animal_LC_100 as other_animal_LC_100, b.other_animal_LCL0 as other_animal_LCL0, b.other_animal_TCL0 as other_animal_TCL0, b.rabbit_percutaneous as rabbit_percutaneous, b.rabbit_meridians as rabbit_meridians, b.rats_percutaneous as rats_percutaneous, b.rats_meridians as rats_meridians, b.guinea_pigs_percutaneous as guinea_pigs_percutaneous, b.guinea_pigs_meridians as guinea_pigs_meridians, b.men_percutaneous as men_percutaneous, b.men_meridians as men_meridians, b.human_percutaneous as human_percutaneous, b.human_meridians as human_meridians, b.subacute_versus_chronic_toxicity as subacute_versus_chronic_toxicity, b.sensitization as sensitization, b.mutagenicity as mutagenicity, b.teratogenicity as teratogenicity, b.carcinogenicity as carcinogenicity, b.other as other, b.absolute_lethal_amount_LD as absolute_lethal_amount_LD, b.half_lethal_dose_LD as half_lethal_dose_LD, b.half_lethal_concentration_LC as half_lethal_concentration_LC, b.half_of_the_effect_concentration_EC as half_of_the_effect_concentration_EC, b.half_of_the_inhibitory_concentration_IC as half_of_the_inhibitory_concentration_IC, b.no_action_dose_NOEL as no_action_dose_NOEL, b.half_of_the_resistance_to_limited_amount_TLm as half_of_the_resistance_to_limited_amount_TLm, b.bod5 as bod5, b.soil_half_life_high as soil_half_life_high, b.soil_half_life_low as soil_half_life_low, b.air_half_life_high as air_half_life_high, b.air_half_life_low as air_half_life_low, b.surface_water_half_life_high as surface_water_half_life_high, b.surface_water_half_life_low as surface_water_half_life_low, b.groundwater_half_life_high as groundwater_half_life_high, b.groundwater_half_life_low as groundwater_half_life_low, b.aqueous_biodegradation_aerobic_high as aqueous_biodegradation_aerobic_high, b.aqueous_biodegradation_aerobic_low as aqueous_biodegradation_aerobic_low, b.aqueous_biodegradation_anaerobics_high as aqueous_biodegradation_anaerobics_high, b.aqueous_biodegradation_anaerobics_low as aqueous_biodegradation_anaerobics_low, b.aqueous_biodegradation_secondary_sedimentation_treatment_high as aqueous_biodegradation_secondary_sedimentation_treatment_high, b.aqueous_biodegradation_secondary_sedimentation_treatment_low as aqueous_biodegradation_secondary_sedimentation_treatment_low, b.aqueous_photolysis_half_life_high as aqueous_photolysis_half_life_high, b.aqueous_photolysis_half_life_low as aqueous_photolysis_half_life_low, b.photolysis_maximal_light_absorption_high as photolysis_maximal_light_absorption_high, b.photolysis_maximal_light_absorption_low as photolysis_maximal_light_absorption_low, b.photooxidation_half_life_in_water_high as photooxidation_half_life_in_water_high, b.photooxidation_half_life_in_water_low as photooxidation_half_life_in_water_low, b.photooxidative_half_life_in_air_high as photooxidative_half_life_in_air_high, b.photooxidative_half_life_in_air_low as photooxidative_half_life_in_air_low, b.reduction_half_life_high as reduction_half_life_high, b.reduction_half_life_low as reduction_half_life_low, b.primary_hydrolysis_half_life as primary_hydrolysis_half_life, b.hydrolysis_in_air_high as hydrolysis_in_air_high, b.hydrolysis_in_air_low as hydrolysis_in_air_low, b.cod as cod, b.bioconcentration_or_bioaccumulation as bioconcentration_or_bioaccumulation, b.other_harmful_effects as other_harmful_effects from msds a left join msds_material b on b.msds = a.id where a.id = #{id} select a.id, a.chemical_cn, a.other_chemical_cn, a.chemical_en, a.other_chemical_en, a.cas, a.type, a.detonator_profession1, a.detonator_profession1_concentration, a.detonator_profession1_CAS_No, a.detonator_profession2, a.detonator_profession2_concentration, a.detonator_profession2_CAS_No, a.detonator_profession3, a.detonator_profession3_concentration, a.detonator_profession3_CAS_No, a.detonator_profession4, a.detonator_profession4_concentration, a.detonator_profession4_CAS_No, a.detonator_profession5, a.detonator_profession5_concentration, a.detonator_profession5_CAS_No, a.hazard_category, a.Invasion_route, a.health_hazards, a.environmental_hazards, a.explosion_hazard, a.skin_contact, a.eye_contact, a.inhalation, a.ingestion, a.hazard_characteristics, a.hazardous_combustion_products, a.fire_extinguishing_method, a.fire_fighting, a.emergency_actions, a.operational_considerations, a.storage_precautions, a.MAC, a.PC_TWA, a.PC_STEL, a.TLV_C, a.TLV_TWA, a.TLV_STEL, a.monitoring_methods, a.engineering_control, a.respiratory_protection, a.eye_protection, a.physical_protection, a.hand_protection, a.other_protection, a.appearance_and_shape, a.ph_value, a.melting_point, a.boiling_point, a.relative_density, a.relative_vapor_density, a.saturated_vapor_pressure, a.heat_of_combustion, a.critical, a.critical_pressure, a.octanol_water_partition_coefficient, a.flash_point, a.Ignition_temperature, a.lower_explosion_limit, a.upper_explosion_limit, a.solubility, a.main_uses, a.stability, a.forbidden_mixtures, a.avoid_contact_conditions, a.aggregation_hazards, a.decomposition_products, a.nature_of_waste, a.disposal_methods, a.deprecation_considerations, a.dangerous_goods_number, a.un_number, a.packaging_category, a.packaging_logo, a.packaging_method, a.shipping_precautions, a.regulatory_information, a.critical_value from msds a where a.chemical_cn = #{name} select a.id, a.chemical_cn, a.other_chemical_cn, a.chemical_en, a.other_chemical_en, a.cas, a.type, a.detonator_profession1, a.detonator_profession1_concentration, a.detonator_profession1_CAS_No, a.detonator_profession2, a.detonator_profession2_concentration, a.detonator_profession2_CAS_No, a.detonator_profession3, a.detonator_profession3_concentration, a.detonator_profession3_CAS_No, a.detonator_profession4, a.detonator_profession4_concentration, a.detonator_profession4_CAS_No, a.detonator_profession5, a.detonator_profession5_concentration, a.detonator_profession5_CAS_No, a.hazard_category, a.Invasion_route, a.health_hazards, a.environmental_hazards, a.explosion_hazard, a.skin_contact, a.eye_contact, a.inhalation, a.ingestion, a.hazard_characteristics, a.hazardous_combustion_products, a.fire_extinguishing_method, a.fire_fighting, a.emergency_actions, a.operational_considerations, a.storage_precautions, a.MAC, a.PC_TWA, a.PC_STEL, a.TLV_C, a.TLV_TWA, a.TLV_STEL, a.monitoring_methods, a.engineering_control, a.respiratory_protection, a.eye_protection, a.physical_protection, a.hand_protection, a.other_protection, a.appearance_and_shape, a.ph_value, a.melting_point, a.boiling_point, a.relative_density, a.relative_vapor_density, a.saturated_vapor_pressure, a.heat_of_combustion, a.critical, a.critical_pressure, a.octanol_water_partition_coefficient, a.flash_point, a.Ignition_temperature, a.lower_explosion_limit, a.upper_explosion_limit, a.solubility, a.main_uses, a.stability, a.forbidden_mixtures, a.avoid_contact_conditions, a.aggregation_hazards, a.decomposition_products, a.nature_of_waste, a.disposal_methods, a.deprecation_considerations, a.dangerous_goods_number, a.un_number, a.packaging_category, a.packaging_logo, a.packaging_method, a.shipping_precautions, a.regulatory_information, a.critical_value, b.msds as msds, b.acute_toxicity as acute_toxicity, b.rats_oral_LD as rats_oral_LD, b.rats_percutaneous_LD as rats_percutaneous_LD, b.rats_subcutaneous_LD as rats_subcutaneous_LD, b.rats_venous_LD as rats_venous_LD, b.rats_intraperitoneal_LD as rats_intraperitoneal_LD, b.mice_oral_LD as mice_oral_LD, b.mice_percutaneous_LD as mice_percutaneous_LD, b.mice_venous_LD as mice_venous_LD, b.mice_intraperitoneal_LD as mice_intraperitoneal_LD, b.guinea_pigs_oral_LD as guinea_pigs_oral_LD, b.guinea_pigs_percutaneous_LD as guinea_pigs_percutaneous_LD, b.guinea_pigs_subcutaneous_LD as guinea_pigs_subcutaneous_LD, b.guinea_pigs_venous_LD as guinea_pigs_venous_LD, b.guinea_pigs_intraperitoneal_LD as guinea_pigs_intraperitoneal_LD, b.rabbit_oral_LD as rabbit_oral_LD, b.rabbit_percutaneous_LD as rabbit_percutaneous_LD, b.rabbit_subcutaneous_LD as rabbit_subcutaneous_LD, b.rabbit_venous_LD as rabbit_venous_LD, b.rabbit_intraperitoneal_LD as rabbit_intraperitoneal_LD, b.other_animal_LD as other_animal_LD, b.LD as LD, b.LDL0 as LDL0, b.TDL0 as TDL0, b.rats_inhale_LC as rats_inhale_LC, b.rats_inhale_LCL0 as rats_inhale_LCL0, b.mice_inhale_LC as mice_inhale_LC, b.mice_inhale_LCL0 as mice_inhale_LCL0, b.mice_inhale_TDL0 as mice_inhale_TDL0, b.people_inhale_LCL0 as people_inhale_LCL0, b.people_inhale_TDL0 as people_inhale_TDL0, b.IDLH as IDLH, b.other_animal_LC_50 as other_animal_LC_50, b.other_animal_LC_100 as other_animal_LC_100, b.other_animal_LCL0 as other_animal_LCL0, b.other_animal_TCL0 as other_animal_TCL0, b.rabbit_percutaneous as rabbit_percutaneous, b.rabbit_meridians as rabbit_meridians, b.rats_percutaneous as rats_percutaneous, b.rats_meridians as rats_meridians, b.guinea_pigs_percutaneous as guinea_pigs_percutaneous, b.guinea_pigs_meridians as guinea_pigs_meridians, b.men_percutaneous as men_percutaneous, b.men_meridians as men_meridians, b.human_percutaneous as human_percutaneous, b.human_meridians as human_meridians, b.subacute_versus_chronic_toxicity as subacute_versus_chronic_toxicity, b.sensitization as sensitization, b.mutagenicity as mutagenicity, b.teratogenicity as teratogenicity, b.carcinogenicity as carcinogenicity, b.other as other, b.absolute_lethal_amount_LD as absolute_lethal_amount_LD, b.half_lethal_dose_LD as half_lethal_dose_LD, b.half_lethal_concentration_LC as half_lethal_concentration_LC, b.half_of_the_effect_concentration_EC as half_of_the_effect_concentration_EC, b.half_of_the_inhibitory_concentration_IC as half_of_the_inhibitory_concentration_IC, b.no_action_dose_NOEL as no_action_dose_NOEL, b.half_of_the_resistance_to_limited_amount_TLm as half_of_the_resistance_to_limited_amount_TLm, b.bod5 as bod5, b.soil_half_life_high as soil_half_life_high, b.soil_half_life_low as soil_half_life_low, b.air_half_life_high as air_half_life_high, b.air_half_life_low as air_half_life_low, b.surface_water_half_life_high as surface_water_half_life_high, b.surface_water_half_life_low as surface_water_half_life_low, b.groundwater_half_life_high as groundwater_half_life_high, b.groundwater_half_life_low as groundwater_half_life_low, b.aqueous_biodegradation_aerobic_high as aqueous_biodegradation_aerobic_high, b.aqueous_biodegradation_aerobic_low as aqueous_biodegradation_aerobic_low, b.aqueous_biodegradation_anaerobics_high as aqueous_biodegradation_anaerobics_high, b.aqueous_biodegradation_anaerobics_low as aqueous_biodegradation_anaerobics_low, b.aqueous_biodegradation_secondary_sedimentation_treatment_high as aqueous_biodegradation_secondary_sedimentation_treatment_high, b.aqueous_biodegradation_secondary_sedimentation_treatment_low as aqueous_biodegradation_secondary_sedimentation_treatment_low, b.aqueous_photolysis_half_life_high as aqueous_photolysis_half_life_high, b.aqueous_photolysis_half_life_low as aqueous_photolysis_half_life_low, b.photolysis_maximal_light_absorption_high as photolysis_maximal_light_absorption_high, b.photolysis_maximal_light_absorption_low as photolysis_maximal_light_absorption_low, b.photooxidation_half_life_in_water_high as photooxidation_half_life_in_water_high, b.photooxidation_half_life_in_water_low as photooxidation_half_life_in_water_low, b.photooxidative_half_life_in_air_high as photooxidative_half_life_in_air_high, b.photooxidative_half_life_in_air_low as photooxidative_half_life_in_air_low, b.reduction_half_life_high as reduction_half_life_high, b.reduction_half_life_low as reduction_half_life_low, b.primary_hydrolysis_half_life as primary_hydrolysis_half_life, b.hydrolysis_in_air_high as hydrolysis_in_air_high, b.hydrolysis_in_air_low as hydrolysis_in_air_low, b.cod as cod, b.bioconcentration_or_bioaccumulation as bioconcentration_or_bioaccumulation, b.other_harmful_effects as other_harmful_effects from msds a left join msds_material b on b.msds = a.id where 1=1 and a.chemical_cn like "%"#{selectValue}"%" and a.other_chemical_cn like "%"#{selectValue}"%" and a.chemical_en like "%"#{selectValue}"%" and a.other_chemical_en like "%"#{selectValue}"%" and a.cas like "%"#{selectValue}"%" and a.dangerous_goods_number like "%"#{selectValue}"%" insert into msds ( chemical_cn, other_chemical_cn, chemical_en, other_chemical_en, cas, type, detonator_profession1, detonator_profession1_concentration, detonator_profession1_CAS_No, detonator_profession2, detonator_profession2_concentration, detonator_profession2_CAS_No, detonator_profession3, detonator_profession3_concentration, detonator_profession3_CAS_No, detonator_profession4, detonator_profession4_concentration, detonator_profession4_CAS_No, detonator_profession5, detonator_profession5_concentration, detonator_profession5_CAS_No, hazard_category, Invasion_route, health_hazards, environmental_hazards, explosion_hazard, skin_contact, eye_contact, inhalation, ingestion, hazard_characteristics, hazardous_combustion_products, fire_extinguishing_method, fire_fighting, emergency_actions, operational_considerations, storage_precautions, MAC, PC_TWA, PC_STEL, TLV_C, TLV_TWA, TLV_STEL, monitoring_methods, engineering_control, respiratory_protection, eye_protection, physical_protection, hand_protection, other_protection, appearance_and_shape, ph_value, melting_point, boiling_point, relative_density, relative_vapor_density, saturated_vapor_pressure, heat_of_combustion, critical, critical_pressure, octanol_water_partition_coefficient, flash_point, Ignition_temperature, lower_explosion_limit, upper_explosion_limit, solubility, main_uses, stability, forbidden_mixtures, avoid_contact_conditions, aggregation_hazards, decomposition_products, nature_of_waste, disposal_methods, deprecation_considerations, dangerous_goods_number, un_number, packaging_category, packaging_logo, packaging_method, shipping_precautions, regulatory_information, critical_value) values ( #{msds.chemicalCn}, #{msds.otherChemicalCn}, #{msds.chemicalEn}, #{msds.otherChemicalEn}, #{msds.cas}, #{msds.type}, #{msds.detonatorProfession1}, #{msds.detonatorProfession1Concentration}, #{msds.detonatorProfession1CasNo}, #{msds.detonatorProfession2}, #{msds.detonatorProfession2Concentration}, #{msds.detonatorProfession2CasNo}, #{msds.detonatorProfession3}, #{msds.detonatorProfession3Concentration}, #{msds.detonatorProfession3CasNo}, #{msds.detonatorProfession4}, #{msds.detonatorProfession4Concentration}, #{msds.detonatorProfession4CasNo}, #{msds.detonatorProfession5}, #{msds.detonatorProfession5Concentration}, #{msds.detonatorProfession5CasNo}, #{msds.hazardCategory}, #{msds.invasionRoute}, #{msds.healthHazards}, #{msds.environmentalHazards}, #{msds.explosionHazard}, #{msds.skinContact}, #{msds.eyeContact}, #{msds.inhalation}, #{msds.ingestion}, #{msds.hazardCharacteristics}, #{msds.hazardousCombustionProducts}, #{msds.fireExtinguishingMethod}, #{msds.fireFighting}, #{msds.emergencyActions}, #{msds.operationalConsiderations}, #{msds.storagePrecautions}, #{msds.mac}, #{msds.pcTwa}, #{msds.pcStel}, #{msds.tlvC}, #{msds.tlvTwa}, #{msds.tlvStel}, #{msds.monitoringMethods}, #{msds.engineeringControl}, #{msds.respiratoryProtection}, #{msds.eyeProtection}, #{msds.physicalProtection}, #{msds.handProtection}, #{msds.otherProtection}, #{msds.appearanceAndShape}, #{msds.phValue}, #{msds.meltingPoint}, #{msds.boilingPoint}, #{msds.relativeDensity}, #{msds.relativeVaporDensity}, #{msds.saturatedVaporPressure}, #{msds.heatOfCombustion}, #{msds.critical}, #{msds.criticalPressure}, #{msds.octanolWaterPartitionCoefficient}, #{msds.flashPoint}, #{msds.ignitionTemperature}, #{msds.lowerExplosionLimit}, #{msds.upperExplosionLimit}, #{msds.solubility}, #{msds.mainUses}, #{msds.stability}, #{msds.forbiddenMixtures}, #{msds.avoidContactConditions}, #{msds.aggregationHazards}, #{msds.decompositionProducts}, #{msds.natureOfWaste}, #{msds.disposalMethods}, #{msds.deprecationConsiderations}, #{msds.dangerousGoodsNumber}, #{msds.unNumber}, #{msds.packagingCategory}, #{msds.packagingLogo}, #{msds.packagingMethod}, #{msds.shippingPrecautions}, #{msds.regulatoryInformation}, #{msds.criticalValue} ) select LAST_INSERT_ID() insert into msds_material ( msds, acute_toxicity, rats_oral_LD, rats_percutaneous_LD, rats_subcutaneous_LD, rats_venous_LD, rats_intraperitoneal_LD, mice_oral_LD, mice_percutaneous_LD, mice_venous_LD, mice_intraperitoneal_LD, guinea_pigs_oral_LD, guinea_pigs_percutaneous_LD, guinea_pigs_subcutaneous_LD, guinea_pigs_venous_LD, guinea_pigs_intraperitoneal_LD, rabbit_oral_LD, rabbit_percutaneous_LD, rabbit_subcutaneous_LD, rabbit_venous_LD, rabbit_intraperitoneal_LD, other_animal_LD, LD, LDL0, TDL0, rats_inhale_LC, rats_inhale_LCL0, mice_inhale_LC, mice_inhale_LCL0, mice_inhale_TDL0, people_inhale_LCL0, people_inhale_TDL0, IDLH, other_animal_LC_50, other_animal_LC_100, other_animal_LCL0, other_animal_TCL0, rabbit_percutaneous, rabbit_meridians, rats_percutaneous, rats_meridians, guinea_pigs_percutaneous, guinea_pigs_meridians, men_percutaneous, men_meridians, human_percutaneous, human_meridians, subacute_versus_chronic_toxicity, sensitization, mutagenicity, teratogenicity, carcinogenicity, other, absolute_lethal_amount_LD, half_lethal_dose_LD, half_lethal_concentration_LC, half_of_the_effect_concentration_EC, half_of_the_inhibitory_concentration_IC, no_action_dose_NOEL, half_of_the_resistance_to_limited_amount_TLm, bod5, soil_half_life_high, soil_half_life_low, air_half_life_high, air_half_life_low, surface_water_half_life_high, surface_water_half_life_low, groundwater_half_life_high, groundwater_half_life_low, aqueous_biodegradation_aerobic_high, aqueous_biodegradation_aerobic_low, aqueous_biodegradation_anaerobics_high, aqueous_biodegradation_anaerobics_low, aqueous_biodegradation_secondary_sedimentation_treatment_high, aqueous_biodegradation_secondary_sedimentation_treatment_low, aqueous_photolysis_half_life_high, aqueous_photolysis_half_life_low, photolysis_maximal_light_absorption_high, photolysis_maximal_light_absorption_low, photooxidation_half_life_in_water_high, photooxidation_half_life_in_water_low, photooxidative_half_life_in_air_high, photooxidative_half_life_in_air_low, reduction_half_life_high, reduction_half_life_low, primary_hydrolysis_half_life, hydrolysis_in_air_high, hydrolysis_in_air_low, cod, bioconcentration_or_bioaccumulation, other_harmful_effects ) values ( #{material.msds}, #{material.acute_toxicity}, #{material.rats_oral_LD}, #{material.rats_percutaneous_LD}, #{material.rats_subcutaneous_LD}, #{material.rats_venous_LD}, #{material.rats_intraperitoneal_LD}, #{material.mice_oral_LD}, #{material.mice_percutaneous_LD}, #{material.mice_venous_LD}, #{material.mice_intraperitoneal_LD}, #{material.guinea_pigs_oral_LD}, #{material.guinea_pigs_percutaneous_LD}, #{material.guinea_pigs_subcutaneous_LD}, #{material.guinea_pigs_venous_LD}, #{material.guinea_pigs_intraperitoneal_LD}, #{material.rabbit_oral_LD}, #{material.rabbit_percutaneous_LD}, #{material.rabbit_subcutaneous_LD}, #{material.rabbit_venous_LD}, #{material.rabbit_intraperitoneal_LD}, #{material.other_animal_LD}, #{material.LD}, #{material.LDL0}, #{material.TDL0}, #{material.rats_inhale_LC}, #{material.rats_inhale_LCL0}, #{material.mice_inhale_LC}, #{material.mice_inhale_LCL0}, #{material.mice_inhale_TDL0}, #{material.people_inhale_LCL0}, #{material.people_inhale_TDL0}, #{material.IDLH}, #{material.other_animal_LC_50}, #{material.other_animal_LC_100}, #{material.other_animal_LCL0}, #{material.other_animal_TCL0}, #{material.rabbit_percutaneous}, #{material.rabbit_meridians}, #{material.rats_percutaneous}, #{material.rats_meridians}, #{material.guinea_pigs_percutaneous}, #{material.guinea_pigs_meridians}, #{material.men_percutaneous}, #{material.men_meridians}, #{material.human_percutaneous}, #{material.human_meridians}, #{material.subacute_versus_chronic_toxicity}, #{material.sensitization}, #{material.mutagenicity}, #{material.teratogenicity}, #{material.carcinogenicity}, #{material.other}, #{material.absolute_lethal_amount_LD}, #{material.half_lethal_dose_LD}, #{material.half_lethal_concentration_LC}, #{material.half_of_the_effect_concentration_EC}, #{material.half_of_the_inhibitory_concentration_IC}, #{material.no_action_dose_NOEL}, #{material.half_of_the_resistance_to_limited_amount_TLm}, #{material.bod5}, #{material.soil_half_life_high}, #{material.soil_half_life_low}, #{material.air_half_life_high}, #{material.air_half_life_low}, #{material.surface_water_half_life_high}, #{material.surface_water_half_life_low}, #{material.groundwater_half_life_high}, #{material.groundwater_half_life_low}, #{material.aqueous_biodegradation_aerobic_high}, #{material.aqueous_biodegradation_aerobic_low}, #{material.aqueous_biodegradation_anaerobics_high}, #{material.aqueous_biodegradation_anaerobics_low}, #{material.aqueous_biodegradation_secondary_sedimentation_treatment_high}, #{material.aqueous_biodegradation_secondary_sedimentation_treatment_low}, #{material.aqueous_photolysis_half_life_high}, #{material.aqueous_photolysis_half_life_low}, #{material.photolysis_maximal_light_absorption_high}, #{material.photolysis_maximal_light_absorption_low}, #{material.photooxidation_half_life_in_water_high}, #{material.photooxidation_half_life_in_water_low}, #{material.photooxidative_half_life_in_air_high}, #{material.photooxidative_half_life_in_air_low}, #{material.reduction_half_life_high}, #{material.reduction_half_life_low}, #{material.primary_hydrolysis_half_life}, #{material.hydrolysis_in_air_high}, #{material.hydrolysis_in_air_low}, #{material.cod}, #{material.bioconcentration_or_bioaccumulation}, #{material.other_harmful_effects} ) update msds_material set acute_toxicity = #{material.acute_toxicity}, rats_oral_LD = #{material.rats_oral_LD}, rats_percutaneous_LD = #{material.rats_percutaneous_LD}, rats_subcutaneous_LD = #{material.rats_subcutaneous_LD}, rats_venous_LD = #{material.rats_venous_LD}, rats_intraperitoneal_LD = #{material.rats_intraperitoneal_LD}, mice_oral_LD = #{material.mice_oral_LD}, mice_percutaneous_LD = #{material.mice_percutaneous_LD}, mice_venous_LD = #{material.mice_venous_LD}, mice_intraperitoneal_LD = #{material.mice_intraperitoneal_LD}, guinea_pigs_oral_LD = #{material.guinea_pigs_oral_LD}, guinea_pigs_percutaneous_LD = #{material.guinea_pigs_percutaneous_LD}, guinea_pigs_subcutaneous_LD = #{material.guinea_pigs_subcutaneous_LD}, guinea_pigs_venous_LD = #{material.guinea_pigs_venous_LD}, guinea_pigs_intraperitoneal_LD = #{material.guinea_pigs_intraperitoneal_LD}, rabbit_oral_LD = #{material.rabbit_oral_LD}, rabbit_percutaneous_LD = #{material.rabbit_percutaneous_LD}, rabbit_subcutaneous_LD = #{material.rabbit_subcutaneous_LD}, rabbit_venous_LD = #{material.rabbit_venous_LD}, rabbit_intraperitoneal_LD = #{material.rabbit_intraperitoneal_LD}, other_animal_LD = #{material.other_animal_LD}, LD = #{material.LD}, LDL0 = #{material.LDL0}, TDL0 = #{material.TDL0}, rats_inhale_LC = #{material.rats_inhale_LC}, rats_inhale_LCL0 = #{material.rats_inhale_LCL0}, mice_inhale_LC = #{material.mice_inhale_LC}, mice_inhale_LCL0 = #{material.mice_inhale_LCL0}, mice_inhale_TDL0 = #{material.mice_inhale_TDL0}, people_inhale_LCL0 = #{material.people_inhale_LCL0}, people_inhale_TDL0 = #{material.people_inhale_TDL0}, IDLH = #{material.IDLH}, other_animal_LC_50 = #{material.other_animal_LC_50}, other_animal_LC_100 = #{material.other_animal_LC_100}, other_animal_LCL0 = #{material.other_animal_LCL0}, other_animal_TCL0 = #{material.other_animal_TCL0}, rabbit_percutaneous = #{material.rabbit_percutaneous}, rabbit_meridians = #{material.rabbit_meridians}, rats_percutaneous = #{material.rats_percutaneous}, rats_meridians = #{material.rats_meridians}, guinea_pigs_percutaneous = #{material.guinea_pigs_percutaneous}, guinea_pigs_meridians = #{material.guinea_pigs_meridians}, men_percutaneous = #{material.men_percutaneous}, men_meridians = #{material.men_meridians}, human_percutaneous = #{material.human_percutaneous}, human_meridians = #{material.human_meridians}, subacute_versus_chronic_toxicity = #{material.subacute_versus_chronic_toxicity}, sensitization = #{material.sensitization}, mutagenicity = #{material.mutagenicity}, teratogenicity = #{material.teratogenicity}, carcinogenicity = #{material.carcinogenicity}, other = #{material.other}, absolute_lethal_amount_LD = #{material.absolute_lethal_amount_LD}, half_lethal_dose_LD = #{material.half_lethal_dose_LD}, half_lethal_concentration_LC = #{material.half_lethal_concentration_LC}, half_of_the_effect_concentration_EC = #{material.half_of_the_effect_concentration_EC}, half_of_the_inhibitory_concentration_IC = #{material.half_of_the_inhibitory_concentration_IC}, no_action_dose_NOEL = #{material.no_action_dose_NOEL}, half_of_the_resistance_to_limited_amount_TLm = #{material.half_of_the_resistance_to_limited_amount_TLm}, bod5 = #{material.bod5}, soil_half_life_high = #{material.soil_half_life_high}, soil_half_life_low = #{material.soil_half_life_low}, air_half_life_high = #{material.air_half_life_high}, air_half_life_low = #{material.air_half_life_low}, surface_water_half_life_high = #{material.surface_water_half_life_high}, surface_water_half_life_low = #{material.surface_water_half_life_low}, groundwater_half_life_high = #{material.groundwater_half_life_high}, groundwater_half_life_low = #{material.groundwater_half_life_low}, aqueous_biodegradation_aerobic_high = #{material.aqueous_biodegradation_aerobic_high}, aqueous_biodegradation_aerobic_low = #{material.aqueous_biodegradation_aerobic_low}, aqueous_biodegradation_anaerobics_high = #{material.aqueous_biodegradation_anaerobics_high}, aqueous_biodegradation_anaerobics_low = #{material.aqueous_biodegradation_anaerobics_low}, aqueous_biodegradation_secondary_sedimentation_treatment_high = #{material.aqueous_biodegradation_secondary_sedimentation_treatment_high}, aqueous_biodegradation_secondary_sedimentation_treatment_low = #{material.aqueous_biodegradation_secondary_sedimentation_treatment_low}, aqueous_photolysis_half_life_high = #{material.aqueous_photolysis_half_life_high}, aqueous_photolysis_half_life_low = #{material.aqueous_photolysis_half_life_low}, photolysis_maximal_light_absorption_high = #{material.photolysis_maximal_light_absorption_high}, photolysis_maximal_light_absorption_low = #{material.photolysis_maximal_light_absorption_low}, photooxidation_half_life_in_water_high = #{material.photooxidation_half_life_in_water_high}, photooxidation_half_life_in_water_low = #{material.photooxidation_half_life_in_water_low}, photooxidative_half_life_in_air_high = #{material.photooxidative_half_life_in_air_high}, photooxidative_half_life_in_air_low = #{material.photooxidative_half_life_in_air_low}, reduction_half_life_high = #{material.reduction_half_life_high}, reduction_half_life_low = #{material.reduction_half_life_low}, primary_hydrolysis_half_life = #{material.primary_hydrolysis_half_life}, hydrolysis_in_air_high = #{material.hydrolysis_in_air_high}, hydrolysis_in_air_low = #{material.hydrolysis_in_air_low}, cod = #{material.cod}, bioconcentration_or_bioaccumulation = #{material.bioconcentration_or_bioaccumulation}, other_harmful_effects = #{material.other_harmful_effects} where msds = #{material.msds} update msds set chemical_cn = #{msds.chemicalCn}, other_chemical_cn = #{msds.otherChemicalCn}, chemical_en = #{msds.chemicalEn}, other_chemical_en = #{msds.otherChemicalEn}, cas = #{msds.cas}, type = #{msds.type}, detonator_profession1 = #{msds.detonatorProfession1}, detonator_profession1_concentration = #{msds.detonatorProfession1Concentration}, detonator_profession1_CAS_No = #{msds.detonatorProfession1CasNo}, detonator_profession2 = #{msds.detonatorProfession2}, detonator_profession2_concentration = #{msds.detonatorProfession2Concentration}, detonator_profession2_CAS_No = #{msds.detonatorProfession2CasNo}, detonator_profession3 = #{msds.detonatorProfession3}, detonator_profession3_concentration = #{msds.detonatorProfession3Concentration}, detonator_profession3_CAS_No = #{msds.detonatorProfession3CasNo}, detonator_profession4 = #{msds.detonatorProfession4}, detonator_profession4_concentration = #{msds.detonatorProfession4Concentration}, detonator_profession4_CAS_No = #{msds.detonatorProfession4CasNo}, detonator_profession5 = #{msds.detonatorProfession5}, detonator_profession5_concentration = #{msds.detonatorProfession5Concentration}, detonator_profession5_CAS_No = #{msds.detonatorProfession5CasNo}, hazard_category = #{msds.hazardCategory}, Invasion_route = #{msds.invasionRoute}, health_hazards = #{msds.healthHazards}, environmental_hazards = #{msds.environmentalHazards}, explosion_hazard = #{msds.explosionHazard}, skin_contact = #{msds.skinContact}, eye_contact = #{msds.eyeContact}, inhalation = #{msds.inhalation}, ingestion = #{msds.ingestion}, hazard_characteristics = #{msds.hazardCharacteristics}, hazardous_combustion_products = #{msds.hazardousCombustionProducts}, fire_extinguishing_method = #{msds.fireExtinguishingMethod}, fire_fighting = #{msds.fireFighting}, emergency_actions = #{msds.emergencyActions}, operational_considerations = #{msds.operationalConsiderations}, storage_precautions = #{msds.storagePrecautions}, MAC = #{msds.mac}, PC_TWA = #{msds.pcTwa}, PC_STEL = #{msds.pcStel}, TLV_C = #{msds.tlvC}, TLV_TWA = #{msds.tlvTwa}, TLV_STEL = #{msds.tlvStel}, monitoring_methods = #{msds.monitoringMethods}, engineering_control = #{msds.engineeringControl}, respiratory_protection = #{msds.respiratoryProtection}, eye_protection = #{msds.eyeProtection}, physical_protection = #{msds.physicalProtection}, hand_protection = #{msds.handProtection}, other_protection = #{msds.otherProtection}, appearance_and_shape = #{msds.appearanceAndShape}, ph_value = #{msds.phValue}, melting_point = #{msds.meltingPoint}, boiling_point = #{msds.boilingPoint}, relative_density = #{msds.relativeDensity}, relative_vapor_density = #{msds.relativeVaporDensity}, saturated_vapor_pressure = #{msds.saturatedVaporPressure}, heat_of_combustion = #{msds.heatOfCombustion}, critical = #{msds.critical}, critical_pressure = #{msds.criticalPressure}, octanol_water_partition_coefficient = #{msds.octanolWaterPartitionCoefficient}, flash_point = #{msds.flashPoint}, Ignition_temperature = #{msds.ignitionTemperature}, lower_explosion_limit = #{msds.lowerExplosionLimit}, upper_explosion_limit = #{msds.upperExplosionLimit}, solubility = #{msds.solubility}, main_uses = #{msds.mainUses}, stability = #{msds.stability}, forbidden_mixtures = #{msds.forbiddenMixtures}, avoid_contact_conditions = #{msds.avoidContactConditions}, aggregation_hazards = #{msds.aggregationHazards}, decomposition_products = #{msds.decompositionProducts}, nature_of_waste = #{msds.natureOfWaste}, disposal_methods = #{msds.disposalMethods}, deprecation_considerations = #{msds.deprecationConsiderations}, dangerous_goods_number = #{msds.dangerousGoodsNumber}, un_number = #{msds.unNumber}, packaging_category = #{msds.packagingCategory}, packaging_logo = #{msds.packagingLogo}, packaging_method = #{msds.packagingMethod}, shipping_precautions = #{msds.shippingPrecautions}, regulatory_information = #{msds.regulatoryInformation}, critical_value = #{msds.criticalValue} where id = #{msds.id} delete from msds where id = #{id} delete from msds_material where msds = #{id} insert into msds_material( id, msds, acute_toxicity, rats_oral_LD, rats_percutaneous_LD, rats_subcutaneous_LD, rats_venous_LD, rats_intraperitoneal_LD, mice_oral_LD, mice_percutaneous_LD, mice_venous_LD, mice_intraperitoneal_LD, guinea_pigs_oral_LD, guinea_pigs_percutaneous_LD, guinea_pigs_subcutaneous_LD, guinea_pigs_venous_LD, guinea_pigs_intraperitoneal_LD, rabbit_oral_LD, rabbit_percutaneous_LD, rabbit_subcutaneous_LD, rabbit_venous_LD, rabbit_intraperitoneal_LD, other_animal_LD, LD, LDL0, TDL0, rats_inhale_LC, rats_inhale_LCL0, mice_inhale_LC, mice_inhale_LCL0, mice_inhale_TDL0, people_inhale_LCL0, people_inhale_TDL0, IDLH, other_animal_LC_50, other_animal_LC_100, other_animal_LCL0, other_animal_TCL0, rabbit_percutaneous, rabbit_meridians, rats_percutaneous, rats_meridians, guinea_pigs_percutaneous, guinea_pigs_meridians, men_percutaneous, men_meridians, human_percutaneous, human_meridians, subacute_versus_chronic_toxicity, sensitization, mutagenicity, teratogenicity, carcinogenicity, other, absolute_lethal_amount_LD, half_lethal_dose_LD, half_lethal_concentration_LC, half_of_the_effect_concentration_EC, half_of_the_inhibitory_concentration_IC, no_action_dose_NOEL, half_of_the_resistance_to_limited_amount_TLm, bod5, soil_half_life_high, soil_half_life_low, air_half_life_high, air_half_life_low, surface_water_half_life_high, surface_water_half_life_low, groundwater_half_life_high, groundwater_half_life_low, aqueous_biodegradation_aerobic_high, aqueous_biodegradation_aerobic_low, aqueous_biodegradation_anaerobics_high, aqueous_biodegradation_anaerobics_low, aqueous_biodegradation_secondary_sedimentation_treatment_high, aqueous_biodegradation_secondary_sedimentation_treatment_low, aqueous_photolysis_half_life_high, aqueous_photolysis_half_life_low, photolysis_maximal_light_absorption_high, photolysis_maximal_light_absorption_low, photooxidation_half_life_in_water_high, photooxidation_half_life_in_water_low, photooxidative_half_life_in_air_high, photooxidative_half_life_in_air_low, reduction_half_life_high, reduction_half_life_low, primary_hydrolysis_half_life, hydrolysis_in_air_high, hydrolysis_in_air_low, cod, bioconcentration_or_bioaccumulation, other_harmful_effects) values ( #{item.id}, #{item.msds}, #{item.acuteToxicity}, #{item.ratsOralLd}, #{item.ratsPercutaneousLd}, #{item.ratsSubcutaneousLd}, #{item.ratsVenousLd}, #{item.ratsIntraperitonealLd}, #{item.miceOralLd}, #{item.micePercutaneousLd}, #{item.miceVenousLd}, #{item.miceIntraperitonealLd}, #{item.guineaPigsOralLd}, #{item.guineaPigsPercutaneousLd}, #{item.guineaPigsSubcutaneousLd}, #{item.guineaPigsVenousLd}, #{item.guineaPigsIntraperitonealLd}, #{item.rabbitOralLd}, #{item.rabbitPercutaneousLd}, #{item.rabbitSubcutaneousLd}, #{item.rabbitVenousLd}, #{item.rabbitIntraperitonealLd}, #{item.otherAnimalLd}, #{item.ld}, #{item.ldl0}, #{item.tdl0}, #{item.ratsInhaleLc}, #{item.ratsInhaleLcl0}, #{item.miceInhaleLc}, #{item.miceInhaleLcl0}, #{item.miceInhaleTdl0}, #{item.peopleInhaleLcl0}, #{item.peopleInhaleTdl0}, #{item.idlh}, #{item.otherAnimalLc50}, #{item.otherAnimalLc100}, #{item.otherAnimalLcl0}, #{item.otherAnimalTcl0}, #{item.rabbitPercutaneous}, #{item.rabbitMeridians}, #{item.ratsPercutaneous}, #{item.ratsMeridians}, #{item.guineaPigsPercutaneous}, #{item.guineaPigsMeridians}, #{item.menPercutaneous}, #{item.menMeridians}, #{item.humanPercutaneous}, #{item.humanMeridians}, #{item.subacuteVersusChronicToxicity}, #{item.sensitization}, #{item.mutagenicity}, #{item.teratogenicity}, #{item.carcinogenicity}, #{item.other}, #{item.absoluteLethalAmountLd}, #{item.halfLethalDoseLd}, #{item.halfLethalConcentrationLc}, #{item.halfOfTheEffectConcentrationEc}, #{item.halfOfTheInhibitoryConcentrationIc}, #{item.noActionDoseNoel}, #{item.halfOfTheResistanceToLimitedAmountTlm}, #{item.bod5}, #{item.soilHalfLifeHigh}, #{item.soilHalfLifeLow}, #{item.airHalfLifeHigh}, #{item.airHalfLifeLow}, #{item.surfaceWaterHalfLifeHigh}, #{item.surfaceWaterHalfLifeLow}, #{item.groundwaterHalfLifeHigh}, #{item.groundwaterHalfLifeLow}, #{item.aqueousBiodegradationAerobicHigh}, #{item.aqueousBiodegradationAerobicLow}, #{item.aqueousBiodegradationAnaerobicsHigh}, #{item.aqueousBiodegradationAnaerobicsLow}, #{item.aqueousBiodegradationSecondarySedimentationTreatmentHigh}, #{item.aqueousBiodegradationSecondarySedimentationTreatmentLow}, #{item.aqueousPhotolysisHalfLifeHigh}, #{item.aqueousPhotolysisHalfLifeLow}, #{item.photolysisMaximalLightAbsorptionHigh}, #{item.photolysisMaximalLightAbsorptionLow}, #{item.photooxidationHalfLifeInWaterHigh}, #{item.photooxidationHalfLifeInWaterLow}, #{item.photooxidativeHalfLifeInAirHigh}, #{item.photooxidativeHalfLifeInAirLow}, #{item.reductionHalfLifeHigh}, #{item.reductionHalfLifeLow}, #{item.primaryHydrolysisHalfLife}, #{item.hydrolysisInAirHigh}, #{item.hydrolysisInAirLow}, #{item.cod}, #{item.bioconcentrationOrBioaccumulation}, #{item.otherHarmfulEffects})